4 methylcyclohexane methanol msds pdf files

How dangerous is the chemical spilled into west virginia. Consult federal, state, andor local authorities for assistance on disposal. Coma resulting from massive exposures may last as long as 2 4 days. West virginia chemical spill declared federal disaster al. See actual entry in rtecs for complete information. The 4methylcyclohexane methanol spill in west virginia coal. Jan 10, 2014 the west virginia chemical spill occurred when a compound called 4 methylcyclohexane methanol leaked from a hole in the bottom of a storage tank, thomas aluise, a wvaw spokesman told the new york. Chemical waste generators must also consult local, regional, and. Vapor or mist is irritating to the eyes, mucous membrane and upper respiratory tract and skin. Mixtures of methanol and water at concentrations greater than 20%. Identification of the substancemixture and of the companyundertaking product information product name. Msds 4methyl1cyclohexanemethanol cis and trans mixture.

Ensure all equipment is electrically grounded before beginning transfer operations. I would normally be wary of putting even something that obvious in, but it seems like making the connection to the naphthenic acids is important, given how much research there is on them. Application of gas chromatography with mass spectrometric and human olfactory sniffer detectors reveals the nature of odorous chemicals from an industrial chemical spill. Hexane 7 section 16 other information msds creation date. Its often confused with other similarly named chemicals that can potentially be lethal. However, the methanol institute assumes no liability whatsoever with respect to the accuracy and completeness of the information, procedures, recommendations and data presented in this technical data sheet.

How dangerous is the chemical spilled into west virginia waters. Hello rchemistry, i live in the charleston, wv area, and currently, 8 counties are in a state or emergency due to a leak of 4methylcyclohexane methanol, a chemical used to clean mining equipment. Immediately flush with plenty of water for at least 15 minutes, if easy to do, remove contact lenses. Disposal considerations waste disposal methods chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Keep away from open flames, hot surfaces and sources of ignition. Safety data sheet methanol bdh15 page 8 16 version 1. A 48,000gallon storage tank along the elk river is leaking a chemical called 4methylcyclohexane methanol. Safety evaluation of certain food additives and contaminants pdf. Methanol in water water in methanol 100% 100% the methanol institute believes the information herein to be accurate. Eastman chemical companys msds for crude unpurified mchm. Methanol safety data sheet according to federal register vol.

Thats where 4methylcyclohexane methanol, mchm for short, comes in. Safety data sheet according to 29cfr19101200 and ghs rev. Product identifier product name ethanol 99,8% chemical name ethyl alcohol synonyms methyl carbinol reach reg no. Information collected included material safety data sheets sds provided to emergency. Show this material safety data sheet to the doctor in attendance. Methanol carbinol methyl hydroxide methylol monohydroxymethane. Coma resulting from massive exposures may last as long as 24 days. In the body, the products formed by its oxidation are formaldehyde and formic acid, both of which are toxic. It is known to pose a significant danger to humans in close contact. Once absorbed, methanol is only very slowly eliminated. Jan 12, 2014 4 methylcyclohexane methanol is a chemical used to clean coal before it is burned. Because of the slow elimination, methanol should be regarded as a cumulative poison. The west virginia chemical spill occurred when a compound called 4methylcyclohexane methanol leaked from a hole in the bottom of a storage tank, thomas aluise, a wvaw spokesman told the new york.

Do not allow product to contact skin, eyes and clothing. Jan 10, 2014 a 48,000gallon storage tank along the elk river is leaking a chemical called 4 methylcyclohexane methanol. Ingestion or exposure to 4mchm can lead to 4methylcyclohexane methanol poisoning. Mchm is used in washing coal, helping separate the burnable fossil fuel from the unburnable rock and dirt and other impurities. Mixtures of methanol and water at concentrations greater than 20% methanol are still considered flammable. Methanol occurs as a flammable, mobile, colorless liquid that is miscible with water. It compiles information from several government agencies and organizations. Yep, that msds certainly does not cover the highpurity compound here is a link. Material safety data sheet risk phrases protective clothing. In animal experiments, methanol has caused fetotoxic or teratogenic effects without maternal toxicity. Other companies are charging thousands of dollars to set up accounts and give you access to their msds online database. Exposure may cause irritation of the skin, eyes, and respiratory system. Cdc niosh pocket guide to chemical hazards methylcyclohexane. First aid for 1hydroxymethyl4methylcyclohexane poisoning.

However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Niosh rel twa 400 ppm 1600 mgm 3 osha pel twa 500 ppm 2000 mgm 3 see. A total of 65% of the dose was excreted in the urine, 15% was eliminated in the expired air 10% as unchanged methylcyclohexane and 5% as carbon dioxide, 0. Absorb with a noncombustible absorbent material such as sand or earth and containerize for disposal. Methanol is considered to be a potential developmental hazard based on animal data. Shortterm exposure can affect breathing, irritate the skin and eyes and cause skin rashes, and inhalation of the compound can damage vital organs and even prove fatal. Identification of the substancemixture and of the companyundertaking date issued 26. As you know a region of southern west virginia where upwards of 100,000 people live has been affected by a spill. Adult chinchilla doe rabbits were administered an oral dose of 2. Predicted data is generated using the us environmental protection agencys episuite. Mar 05, 2018 ingestion or exposure to 4 mchm can lead to 4 methylcyclohexane methanol poisoning. Sep, 2014 register now and get a free online msds binder.

Toxicity of methylcyclohexane and its effect on the. The information provided in this safety data sheet is correct to the best of our knowledge, information and belief at the date of its publication. Chemical product and company identification methanol. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification.

Issued a 14 day drinking water screening level for 4mchm for the inhalation exposure pathway. What links here related changes upload file special pages permanent link. This may be accidental or intentional the condition is diagnosed based upon the clinical history, combination of signs and symptoms, and additional tests that may include, in some cases, radiological studies and laboratory tests. The half lethal concentration lc 50 of methylcyclohexane is known to be 3,750 ppm 15. If the substance is covered by more than one clh entry e. No warranty, express or implied, is made and labchem inc. This chemical inventory is oshas premier onestop shop for occupational chemical information.

Highpurity chemicals usually come with a high price tag, affordable. Liquid may irritate eyes and skin under repeated or prolonged exposure. Breathing high concentrations of product vapor may produce dizziness and nausea. Always wear recommended personal protective equipment. Finish cleaning the spill by rinsing any contaminated surfaces with copious amounts of water. Safety data sheet according to 29cfr1910 1200 and ghs rev. Osha occupational chemical database occupational safety.

None information in this msds is from available published sources and is believed to be accurate. West virginia chemical spill declared federal disaster. Chemical identification and physical properties exposure limits sampling information. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. Incompatible materials strong oxidizing agents, acid anhydrides, acid chlorides. The 4methylcyclohexane methanol spill in west virginia. Jan 09, 2014 west virginia schools and restaurants closed, grocery stores sold out of bottled water, and state legislators who had just started their session canceled the days business friday after a chemical spill in the elk river in charleston shut down much of the city and surrounding counties even as the cause and extent of the incident remained unclear. Olfactory gas chromatography allows investigators to independently measure the odor of each chemical component in a mixture.